Int J Phytoremediation. 2014;16(7-12):1058-72. doi: 10.1080/15226514.2013.810585.
Ni recovery from serpentine soils by phytomining has proved feasible. Phytomining involves the crop of hyperaccumulating plants with high Ni contents and the valorization of Ni by pyro or hydrometallurgical process. In order to evaluate the Ni content of different plants, we analyzed the organs of 14 hyperaccumulators from three genera: Alyssum, Leptoplax and Bornmuellera. The highest concentration was recorded in the leaves of Leptoplax (34.3 +/- 0.7 mg g(-1)DM). Additionally, we investigated biomass combustion which is the first step of the process we designed to obtain a nickel salt. We showed that temperature and duration were important parameters to ensure a good quality of ashes. At the bench scale, the best conditions were 550 degrees C and 3 h. In this way, we obtained ashes in which Ni could reach 20 wt%. Biomass ashes can be considered as a bio-ore for recovering metal value.
通过植物浸矿从蛇纹石中回收镍已被证明是可行的。植物浸矿包括种植镍含量高的超积累植物,以及通过火法或湿法冶金工艺来利用镍。为了评估不同植物的镍含量,我们分析了来自三个属的 14 种超积累植物的器官:菥蓂属、Leptoplax 和 Bornmuellera。在 Leptoplax 的叶片中记录到了最高浓度(34.3 +/- 0.7 mg g(-1)DM)。此外,我们还研究了生物质燃烧,这是我们设计的获得镍盐过程的第一步。我们表明,温度和持续时间是确保灰烬质量的重要参数。在台架规模上,最佳条件是 550°C 和 3 小时。通过这种方式,我们获得了镍含量可达 20wt%的灰烬。生物质灰可以被视为回收金属价值的生物矿石。