四氯合钴（II）酸双（四苯基鏻）
Bis(tetra-phenyl-phospho-nium) tetra-chlorido-cobaltate(II).
作者信息
Ouahida Zeghouan, Hadjadj Nasreddine, Guenifa Fatiha, Bendjeddou Lamia, Merazig Hocine
机构信息
Unité de Recherche Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine, Algeria.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 May 21;70(Pt 6):m229-30. doi: 10.1107/S1600536814011210. eCollection 2014 Jun 1.
The title compound, (C24H20P)2[CoCl4], was prepared under hydro-thermal conditions. In the crystal, the tetra-phenyl-phospho-nium cations are linked by pairs of weak C-H⋯π inter-actions into supra-molecular dimers; the Co(II) cations lie on twofold rotation axes and the tetra-hedral CoCl4 anions are linked with the tetra-phenyl-phospho-nium cations via weak C-H⋯Cl hydrogen bonds.
标题化合物(C24H20P)2[CoCl4]是在水热条件下制备的。在晶体中，四苯基鏻阳离子通过成对的弱C-H⋯π相互作用连接成超分子二聚体；Co(II)阳离子位于二重旋转轴上，四面体CoCl4阴离子通过弱C-H⋯Cl氢键与四苯基鏻阳离子相连。
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