• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

四氯合钴（II）酸双（四苯基鏻）

Bis(tetra-phenyl-phospho-nium) tetra-chlorido-cobaltate(II).

作者信息

Ouahida Zeghouan, Hadjadj Nasreddine, Guenifa Fatiha, Bendjeddou Lamia, Merazig Hocine

机构信息

Unité de Recherche Chimie de l'Environnement et Moléculaire Structurale (CHEMS), Faculté des Sciences Exactes, Campus Chaabet Ersas, Université Constantine I, 25000 Constantine, Algeria.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 May 21;70(Pt 6):m229-30. doi: 10.1107/S1600536814011210. eCollection 2014 Jun 1.

DOI:10.1107/S1600536814011210
PMID:24940211
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4051096/
Abstract

The title compound, (C24H20P)2[CoCl4], was prepared under hydro-thermal conditions. In the crystal, the tetra-phenyl-phospho-nium cations are linked by pairs of weak C-H⋯π inter-actions into supra-molecular dimers; the Co(II) cations lie on twofold rotation axes and the tetra-hedral CoCl4 anions are linked with the tetra-phenyl-phospho-nium cations via weak C-H⋯Cl hydrogen bonds.

摘要

标题化合物(C24H20P)2[CoCl4]是在水热条件下制备的。在晶体中，四苯基鏻阳离子通过成对的弱C-H⋯π相互作用连接成超分子二聚体；Co(II)阳离子位于二重旋转轴上，四面体CoCl4阴离子通过弱C-H⋯Cl氢键与四苯基鏻阳离子相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c15c/4051096/a4a3359168dd/e-70-0m229-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c15c/4051096/c8d5a67440a2/e-70-0m229-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c15c/4051096/686a2fe4a18f/e-70-0m229-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c15c/4051096/a4a3359168dd/e-70-0m229-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c15c/4051096/c8d5a67440a2/e-70-0m229-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c15c/4051096/686a2fe4a18f/e-70-0m229-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c15c/4051096/a4a3359168dd/e-70-0m229-fig3.jpg

相似文献

1
Bis(tetra-phenyl-phospho-nium) tetra-chlorido-cobaltate(II).四氯合钴（II）酸双（四苯基鏻）
Acta Crystallogr Sect E Struct Rep Online. 2014 May 21;70(Pt 6):m229-30. doi: 10.1107/S1600536814011210. eCollection 2014 Jun 1.
2
Crystal structure of bis-(acetonyltri-phenyl-phospho-nium) tetra-chlorido-cobaltate(II).二（丙酮基三苯基鏻）四氯合钴（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Nov 4;71(Pt 12):m209-10. doi: 10.1107/S2056989015019180. eCollection 2015 Dec 1.
3
Acetonyltri-phenyl-phospho-nium 2,3,5-tri-phenyl-tetra-zolium tetra-chlorido-cuprate(II).丙酮基三苯基鏻四氯合铜（II）2,3,5-三苯基四唑鎓盐
Acta Crystallogr E Crystallogr Commun. 2018 Jan 1;74(Pt 1):69-71. doi: 10.1107/S205698901701800X.
4
Crystal structures of bis-[(9,13,14)-3-meth-oxy-17-methyl-morphinanium] tetra-chlorido-cobaltate and tetra-chlorido-cuprate.双-[(9,13,14)-3-甲氧基-17-甲基-吗啉鎓]四氯合钴酸盐和四氯合铜酸盐的晶体结构
Acta Crystallogr E Crystallogr Commun. 2017 Jan 1;73(Pt 1):63-67. doi: 10.1107/S2056989016019939.
5
Bis(tetra-phenyl-phospho-nium) tetra-sulfido-tungstate(VI).双（四苯基鏻）四硫代钨酸盐（VI）
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 29;64(Pt 4):m574. doi: 10.1107/S1600536808007472.
6
Crystal structure of bis-(2-methyl-1H-imidazol-3-ium) tetra-chlorido-cobaltate(II).二（2-甲基-1H-咪唑-3-鎓）四氯合钴（II）酸盐的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Aug 22;71(Pt 9):1064-6. doi: 10.1107/S2056989015014127. eCollection 2015 Sep 1.
7
Crystal structure of bis-(4-acetyl-anilinium) tetra-chlorido-cobaltate(II).双（4-乙酰基苯胺鎓）四氯合钴（II）酸盐的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Nov 18;71(Pt 12):m221-2. doi: 10.1107/S2056989015021404. eCollection 2015 Dec 1.
8
Crystal structure of bis-(tetra-phenyl-phospho-nium) bis-(cyanido-κC)(29H,31H-tetra-benzo[b,g,l,q]porphinato-κ(4) N (29),N (30),N (31),N (32))ferrate(II) acetone disolvate.双（四苯基鏻）双（氰基-κC）（29H，31H-四苯并[b，g，l，q]卟啉合-κ(4)N(29)，N(30)，N(31)，N(32)）铁（II）丙酮溶剂化物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 31;71(Pt 2):m48-9. doi: 10.1107/S2056989015001735. eCollection 2015 Feb 1.
9
Crystal structure and Hirshfeld surface analysis of bis-(2,6-di-amino-pyridinium) tetra-chlorido-cobaltate(II).二（2,6 - 二氨基吡啶鎓）四氯合钴（II）酸盐的晶体结构与 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2018 Mar 2;74(Pt 4):436-440. doi: 10.1107/S2056989018003171. eCollection 2018 Apr 1.
10
Bis(tetra-phenyl-phospho-nium) bis-[N-(trifluoro-methyl-sulfon-yl)dithio-carbimato(2-)-κS,S']zincate(II).双（四苯基鏻）双-[N-（三氟甲基磺酰基）二硫代氨基甲酸盐（2-）-κS，S']锌酸盐（II）
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m33-4. doi: 10.1107/S160053681105207X. Epub 2011 Dec 10.

本文引用的文献

1
Single-crystal to single-crystal structural transformation and photomagnetic properties of a porous iron(II) spin-crossover framework.一种多孔铁（II）自旋交叉框架的单晶到单晶结构转变及光磁性质
J Am Chem Soc. 2008 Mar 5;130(9):2869-76. doi: 10.1021/ja077958f. Epub 2008 Feb 7.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Poly[tetraphenylphosphonium copper(I)-di-micro2-dicyanamido].聚[四苯基鏻铜（I）-双-μ2-二氰胺基]
Acta Crystallogr C. 2007 Jun;63(Pt 6):m235-7. doi: 10.1107/S0108270107015387. Epub 2007 May 11.
4
[Cu(C24H22N4O3)].CH2Cl2: a discrete breathing metallamacrocycle showing selective and reversible guest adsorption with retention of single crystallinity.[Cu(C₂₄H₂₂N₄O₃)].CH₂Cl₂：一种离散的呼吸型金属大环化合物，表现出选择性和可逆的客体吸附，并保持单晶性。
J Am Chem Soc. 2007 Feb 14;129(6):1514-5. doi: 10.1021/ja067384z. Epub 2007 Jan 24.
5
Strategies for hydrogen storage in metal--organic frameworks.金属有机框架中氢气储存的策略。
Angew Chem Int Ed Engl. 2005 Jul 25;44(30):4670-9. doi: 10.1002/anie.200462786.
6
A nanotubular 3D coordination polymer based on a 3d-4f heterometallic assembly.
Angew Chem Int Ed Engl. 2003 Feb 24;42(8):934-6. doi: 10.1002/anie.200390248.