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4-氮鎓基-2,2,6,6-四甲基哌啶-1-鎓二硝酸盐

4-Aza-niumyl-2,2,6,6-tetra-methyl-piperidin-1-ium dinitrate.

作者信息

Chebbi Hammouda, Ben Smail Ridha, Zid Mohamed Faouzi

机构信息

Institut Préparatoire aux Etudes d'Ingénieurs de Monastir, Avenue Ibn-El-Jazzar, 5019 Monastir, Tunisia ; Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, 2092 El Manar II, Tunis, Tunisia.

Institut Préparatoire aux Etudes d'Ingénieurs de Nabeul, Campus Universitaire Mrazka, 8000 Nabeul, Tunisia ; Laboratoire de Matériaux et Cristallochimie, Faculté des Sciences de Tunis, 2092 El Manar II, Tunis, Tunisia.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 May 10;70(Pt 6):o642. doi: 10.1107/S1600536814009787. eCollection 2014 Jun 1.

DOI:10.1107/S1600536814009787
PMID:24940229
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4051017/
Abstract

In the crystal structure of the title salt, C9H22N2 (2+)·2NO3 (-), the piperidine ring of the dication adopts a chair conformation and the orientation of the C-NH3 bond is equatorial. The ions are linked by normal and bifurcated N-H⋯O hydrogen bonds in R 2 (2)(6), two R 4 (2)(8) and R 3 (4)(14) graf-set motifs, generating a three-dimensional network.

摘要

在标题盐C9H22N2(2+)·2NO3(-)的晶体结构中,二价阳离子的哌啶环呈椅式构象,C-NH3键的取向为平伏键。离子通过R2(2)(6)中的正常和分叉N-H⋯O氢键、两个R4(2)(8)和R3(4)(14)图式 motif相连,形成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3968/4051017/9ddd9a67c6d1/e-70-0o642-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3968/4051017/bc063e335a11/e-70-0o642-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3968/4051017/f43d3734bab6/e-70-0o642-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3968/4051017/9ddd9a67c6d1/e-70-0o642-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3968/4051017/bc063e335a11/e-70-0o642-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3968/4051017/f43d3734bab6/e-70-0o642-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3968/4051017/9ddd9a67c6d1/e-70-0o642-fig3.jpg

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