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(E)-2,3-双-[(E)-(2-甲基-2-苯基肼-1-基亚甲基)]丁二酸二乙酯

Diethyl (E)-2,3-bis-[(E)-(2-methyl-2-phenyl-hydrazin-1-yl-idene)meth-yl]but-2-enedioate.

作者信息

Liu Peng, Yuan Libin, Song Xiuqing, Yan Hong

机构信息

College of Life Science and Bio-engineering, Beijing University of Technology, Pingleyuan Street No. 100, Chaoyang District, Beijing 100124, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 May 31;70(Pt 6):o723. doi: 10.1107/S1600536814011970. eCollection 2014 Jun 1.

Abstract

The complete mol-ecule of the title compound, C24H28N4O4, is generated by crystallographic inversion symmetry. The ethyl side chain is disordered over two sets of sites in a 0.57 (4):0.43 (4) ratio. The dihedral angles between the methyl-idene group and the phenyl ring and ester side chain (major conformation) are 7.61 (8) and 86.95 (8)°, respectively. In the crystal, mol-ecules are linked via C-H⋯O hydrogen bonds, forming corrugated sheets lying parallel to (010).

摘要

标题化合物C24H28N4O4的完整分子由晶体学倒转对称性产生。乙基侧链在两组位置上无序排列,比例为0.57 (4):0.43 (4)。亚甲基与苯环和酯侧链(主要构象)之间的二面角分别为7.61 (8)°和86.95 (8)°。在晶体中,分子通过C—H⋯O氢键相连,形成平行于(010)的波纹片层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28d5/4051109/47210caf3a1b/e-70-0o723-fig1.jpg

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本文引用的文献

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