大环中π共轭对一系列硫杂并四苯卟啉类化合物光物理性质的影响。
The effect of π-conjugation in the macrocyclic ring on the photophysical properties of a series of thiaaceneporphyrinoids.
作者信息
Sung Young Mo, Szyszko Bartosz, Myśliborski Radomir, Stępień Marcin, Oh Juwon, Son Minjung, Latos-Grażyński Lechosław, Kim Dongho
机构信息
Department of Chemistry, Yonsei University, Seoul 120-749, Korea.
出版信息
Chem Commun (Camb). 2014 Aug 7;50(61):8367-9. doi: 10.1039/c4cc03855j.
PMID:24943403
Abstract
In a series of thiaaceneporphyrinoids, their conformers exhibit macrocyclic π-conjugation pathways controlled by a dihedral angle between the porphyrin framework and acene planes. Conformational equilibria significantly affect the photophysical properties of these macrocycles.
摘要
在一系列硫杂并四苯卟啉类化合物中，它们的构象异构体呈现出由卟啉骨架与并四苯平面之间的二面角控制的大环π共轭途径。构象平衡显著影响这些大环化合物的光物理性质。
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