Liu Xiang, Guo Dan, Liu Shuhai, Xie Guoxin, Luo Jianbin
State Key Laboratory of Tribology, Tsinghua University , Beijing 100084, China.
Langmuir. 2014 Jul 8;30(26):7695-702. doi: 10.1021/la500287z. Epub 2014 Jun 27.
To simulate the interfacial behaviors in real heterogeneous systems, the point contact condition is constructed to study the classical immiscible displacement problem in this work. Specifically, the interfacial dynamics during the water droplet passing through the oil capillary bridge formed under the point contact condition is investigated. Emphasis is put on the influences of the wettabilities and the relative separation motion of the solid surfaces on the dynamic behavior of the droplets. The observations suggested that the capillary pressure had negligible effect on the movement of the water droplet when it was passing though the oil capillary bridge. The wettability and the relative separation of the disk and ball would influence the final adhesion behaviors of the water droplet after the droplet passed through the oil capillary bridge. Surface tension and adhesion energy were used to interpret these observations.
为了模拟实际非均相系统中的界面行为,本文构建了点接触条件来研究经典的不混溶驱替问题。具体而言,研究了水滴在点接触条件下形成的油毛细管桥中通过时的界面动力学。重点关注固体表面的润湿性和相对分离运动对液滴动力学行为的影响。观察结果表明,水滴通过油毛细管桥时,毛细管压力对其运动的影响可忽略不计。圆盘和球体的润湿性及相对分离会影响水滴通过油毛细管桥后的最终粘附行为。利用表面张力和粘附能来解释这些观察结果。