Li Jitao, Xu Chunxiang, Nan Haiyan, Jiang Mingming, Gao Guangyu, Lin Yi, Dai Jun, Zhu Gangyi, Ni Zhenhua, Wang Shufeng, Li Yan
State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, and ‡Department of Physics, Southeast University , Nanjing 210096, China.
ACS Appl Mater Interfaces. 2014 Jul 9;6(13):10469-75. doi: 10.1021/am502043f. Epub 2014 Jun 27.
Fundamental physics under the surface plasmon (SP) of graphene and the functional application beyond ultraviolet (UV) lasing of ZnO are both fascinating research areas. Herein, the optical field confinement induced by graphene SP was simulated theoretically in a graphene-coated ZnO microrod, which acted as a whispering-gallery microcavity for lasing resonance. Distinct optical field confinement and photoluminescence (PL) enhancement were observed experimentally. Stable and transient spectra were employed to analyze the PL enhancement and the coupling dynamics between graphene SP and ZnO interband emission. As a functional application, the graphene-coated ZnO microcavities presented the obviously improved whispering-gallery mode (WGM) lasing performance. These results would be valuable for designing novel optical and photoelectronic devices based on SP coupling in graphene-semiconductor hybrid materials.
石墨烯表面等离激元(SP)下的基础物理以及氧化锌(ZnO)紫外(UV)激光之外的功能应用都是引人入胜的研究领域。在此,理论上模拟了石墨烯包覆的ZnO微棒中由石墨烯表面等离激元引起的光场限制,该微棒作为用于激光共振的回音壁微腔。实验观察到了明显的光场限制和光致发光(PL)增强。利用稳态和瞬态光谱分析了PL增强以及石墨烯表面等离激元和ZnO带间发射之间的耦合动力学。作为一种功能应用,石墨烯包覆的ZnO微腔展现出明显改善的回音壁模式(WGM)激光性能。这些结果对于基于石墨烯 - 半导体混合材料中的表面等离激元耦合设计新型光学和光电器件具有重要价值。