Zuo Zhenyu, Sun Hongjian, Wang Lin, Li Xiaoyan
School of Chemistry and Chemical Engineering, Key Laboratory of Special Functional Aggregated Materials, Ministry of Education, Shandong University, Shanda Nanlu 27, 250199 Jinan, PR China.
Dalton Trans. 2014 Aug 14;43(30):11716-22. doi: 10.1039/c4dt00944d. Epub 2014 Jun 23.
Two new hydrido iron complexes (2 and 4) were synthesized by the reactions of (4-methoxyphenyl)phenylketimine ((4-MeOPh)PhC=NH) with Fe(PMe3)4 or FeMe2(PMe3)4. The molecular structures of complexes 2 and 4 were confirmed by X-ray single crystal diffraction. Using hydrido iron complexes (1-4) as catalysts, the hydrosilylations of aldehydes and ketones were investigated. The four complexes were effective catalysts for this reduction reaction. Complex 1 among them is the best catalyst.
通过（4-甲氧基苯基）苯基酮亚胺（(4-MeOPh)PhC=NH）与Fe(PMe3)4或FeMe2(PMe3)4反应合成了两种新的氢化铁配合物（2和4）。配合物2和4的分子结构通过X射线单晶衍射得以确认。以氢化铁配合物（1 - 4）为催化剂，研究了醛和酮的硅氢化反应。这四种配合物都是该还原反应的有效催化剂。其中配合物1是最佳催化剂。
