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浸入手性液晶中的均匀和非均匀胶体中的向错线。

Disclination lines at homogeneous and heterogeneous colloids immersed in a chiral liquid crystal.

作者信息

Melle Michael, Schlotthauer Sergej, Hall Carol K, Diaz-Herrera Enrique, Schoen Martin

机构信息

Stranski-Laboratorium für Physikalische und Theoretische Chemie, Fakultät für Mathematik und Naturwissenschaften, Technische Universität Berlin, Straße des 17. Juni 135, 10623 Berlin, Germany.

出版信息

Soft Matter. 2014 Aug 14;10(30):5489-502. doi: 10.1039/c4sm00959b.

Abstract

In the present work we perform Monte Carlo simulations in the isothermal-isobaric ensemble to study defect topologies formed in a cholesteric liquid crystal due to the presence of a spherical colloidal particle. Topological defects arise because of the competition between anchoring at the colloidal surface and the local director. We consider homogeneous colloids with either local homeotropic or planar anchoring to validate our model by comparison with earlier lattice Boltzmann studies. Furthermore, we perform simulations of a colloid in a twisted nematic cell and discuss the difference between induced and intrinsic chirality on the formation of topological defects. We present a simple geometrical argument capable of describing the complex three-dimensional topology of disclination lines evolving near the surface of the colloid. The presence of a Janus colloid in a cholesteric host fluid reveals a rich variety of defect structures. Using the Frank free energy we analyze these defects quantitatively indicating a preferred orientation of the Janus colloid relative to the cholesteric helix.

摘要

在本工作中,我们在等温等压系综中进行蒙特卡罗模拟,以研究由于球形胶体粒子的存在而在胆甾相液晶中形成的缺陷拓扑结构。拓扑缺陷的出现是由于胶体表面的锚定与局部指向矢之间的竞争。我们考虑具有局部垂直或平面锚定的均匀胶体,通过与早期的格子玻尔兹曼研究进行比较来验证我们的模型。此外,我们对扭曲向列相单元中的胶体进行模拟,并讨论诱导手性和固有手性在拓扑缺陷形成上的差异。我们提出了一个简单的几何论证,能够描述在胶体表面附近演化的位错线的复杂三维拓扑结构。胆甾相主体流体中存在的Janus胶体揭示了丰富多样的缺陷结构。利用弗兰克自由能,我们对这些缺陷进行了定量分析,表明了Janus胶体相对于胆甾相螺旋的优选取向。

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