Petit-Garrido Núria, Trivedi Rahul P, Sagués Francesc, Ignés-Mullol Jordi, Smalyukh Ivan I
Departament de Química Física and Institut de Nanociència i Nanotecnologia (IN2UB), Universitat de Barcelona, Martí i Franquès 1, 08028 Barcelona, Catalonia, Spain.
Soft Matter. 2014 Nov 7;10(41):8163-70. doi: 10.1039/c4sm00872c.
Unless stabilized by colloids or confinement with well-defined boundary conditions, defects in liquid crystals remain elusive short-lived objects that tend to disappear with time to minimize the medium's free energy. In this work we use multimodal three-dimensional imaging to visualize cholesteric director structures to show that self-assembled chiral molecular monolayer domains can stabilize topologically constrained defect configurations when in contact with a cholesteric liquid crystal. The cholesteric liquid crystal, having features of both coarse-grained lamellar and nematic liquid crystal with chiral symmetry breaking, allows us to explore the interplay of chirality and implications of layering on the formed defects and director configurations.
除非通过胶体稳定或在具有明确边界条件的限制下,液晶中的缺陷仍然是难以捉摸的短寿命物体,它们往往会随着时间消失,以最小化介质的自由能。在这项工作中,我们使用多模态三维成像来可视化胆甾相指向矢结构,以表明自组装手性分子单层域在与胆甾相液晶接触时可以稳定拓扑受限的缺陷构型。胆甾相液晶兼具粗粒层状液晶和向列相液晶的特征,且具有手性对称性破缺,这使我们能够探索手性的相互作用以及分层对所形成的缺陷和指向矢构型的影响。