Ren Jiangang, Zhang Guocheng, Song Zhimin, Liu Gaofeng, Li Bing
College of Resources and Environment, Henan Polytechnic University, Jiaozuo, Henan 454003, China.
College of Resources and Environment, Henan Polytechnic University, Jiaozuo, Henan 454003, China ; State Key Laboratory Cultivation Base for Gas Geology and Gas Control, Henan Polytechnic University, Jiaozuo, Henan 454003, China.
ScientificWorldJournal. 2014;2014:490318. doi: 10.1155/2014/490318. Epub 2014 May 13.
We selected, as the objects of our research, lignite from the Beizao Mine, gas coal from the Caiyuan Mine, coking coal from the Xiqu Mine, and anthracite from the Guhanshan Mine. We used the mercury intrusion method and the low-temperature liquid nitrogen adsorption method to analyze the structure and shape of the coal pores and calculated the fractal dimensions of different aperture segments in the coal. The experimental results show that the fractal dimension of the aperture segment of lignite, gas coal, and coking coal with an aperture of greater than or equal to 10 nm, as well as the fractal dimension of the aperture segment of anthracite with an aperture of greater than or equal to 100 nm, can be calculated using the mercury intrusion method; the fractal dimension of the coal pore, with an aperture range between 2.03 nm and 361.14 nm, can be calculated using the liquid nitrogen adsorption method, of which the fractal dimensions bounded by apertures of 10 nm and 100 nm are different. Based on these findings, we defined and calculated the comprehensive fractal dimensions of the coal pores and achieved the unity of fractal dimensions for full apertures of coal pores, thereby facilitating, overall characterization for the heterogeneity of the coal pore structure.
我们选取了北皂矿褐煤、蔡园矿气煤、西曲矿焦煤和古汉山矿无烟煤作为研究对象。采用压汞法和低温液氮吸附法分析煤孔隙结构和形态,并计算了煤中不同孔径段的分形维数。实验结果表明:对于孔径大于或等于10nm的褐煤、气煤和焦煤的孔径段分形维数以及孔径大于或等于100nm的无烟煤的孔径段分形维数,可采用压汞法计算;对于孔径范围在2.03nm至361.14nm之间的煤孔隙分形维数,可采用液氮吸附法计算,其中以10nm和100nm孔径为界的分形维数不同。基于这些研究结果,我们定义并计算了煤孔隙综合分形维数,实现了煤孔隙全孔径分形维数的统一,从而便于对煤孔隙结构非均质性进行整体表征。