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一种用于高效溶液处理磷光有机发光二极管的红色发射纯配体铱(III)配合物的简便合成路线。

An easy route to red emitting homoleptic IrIII complex for highly efficient solution-processed phosphorescent organic light-emitting diodes.

作者信息

Giridhar Thota, Han Tae-Hee, Cho Woosum, Saravanan Chinnusamy, Lee Tae-Woo, Jin Sung-Ho

机构信息

Department of Chemistry Education, Graduate Department of Chemical Materials and Institute for Plastic Information and Energy Materials, Pusan National University, Busan, 609-735 (Republic of Korea).

出版信息

Chemistry. 2014 Jul 1;20(27):8260-4. doi: 10.1002/chem.201400243. Epub 2014 Jun 24.

Abstract

A thiophene-phenylquinoline-based homoleptic Ir(III) complex, [Ir(Th-PQ)(3)], has been synthesised by a simple route and utilised as a dopant in solution-processed phosphorescent organic light-emitting diodes (PhOLEDs). It shows the current efficiency of approximately 26 cd A(-1) and the external quantum efficiency of about 21 %, which are the highest values reported to date for PhOLEDs prepared by solution-process.

摘要

一种基于噻吩-苯基喹啉的均配型铱(III)配合物[Ir(Th-PQ)₃]已通过简单方法合成,并用作溶液处理磷光有机发光二极管(PhOLEDs)中的掺杂剂。它显示出约26 cd A⁻¹的电流效率和约21%的外量子效率,这是迄今为止通过溶液处理制备的PhOLEDs所报道的最高值。

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