Mechanochemical synthesis of crystalline and amorphous digold(I) helicates exhibiting anion- and phase-switchable luminescence properties.
作者信息
Jobbágy Csaba, Molnár Miklós, Baranyai Péter, Deák Andrea
机构信息
Hungarian Academy of Sciences, MTA TTK SZKI Lendület Supramolecular Chemistry Laboratory 1117 Budapest, Magyar Tudósok körútja 2, Hungary.
出版信息
Dalton Trans. 2014 Aug 21;43(31):11807-10. doi: 10.1039/c4dt01214c.
PMID:24962131
Abstract
For the first time, mechanochemical synthesis has been used for the preparation of crystalline and amorphous dinuclear gold(i) helicates, Au2L22 (L = xantphos; X = CF3SO3, SCN, BF4 and PF6), that show anion- and phase-switchable luminescence properties. This solid-state approach provides strategies for developing switchable luminescent materials.
摘要
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