具有三元构筑单元的两种微孔金属有机框架材料对天然气的高效气体吸附与分离
High performance gas adsorption and separation of natural gas in two microporous metal-organic frameworks with ternary building units.
作者信息
Wang Dongmei, Zhao Tingting, Cao Yu, Yao Shuo, Li Guanghua, Huo Qisheng, Liu Yunling
机构信息
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China.
出版信息
Chem Commun (Camb). 2014 Aug 14;50(63):8648-50. doi: 10.1039/c4cc03729d. Epub 2014 Jun 27.
PMID:24969667
Abstract
Two novel MMOFs, JLU-Liu5 and JLU-Liu6, are based on ternary building units and exhibit high adsorption selectivity for CO2, C2H6 and C3H8 over CH4, which is attributed to steric effects and host-guest interactions. These MMOFs are promising materials for gas adsorption and natural gas purification.
摘要
两种新型金属有机金属框架材料JLU-Liu5和JLU-Liu6基于三元构建单元，对二氧化碳、乙烷和丙烷相对于甲烷表现出高吸附选择性，这归因于空间效应和主客体相互作用。这些金属有机金属框架材料是用于气体吸附和天然气净化的有前景的材料。
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