Dumitrescu Dan, Legrand Yves-Marie, Petit Eddy, van der Lee Arie, Barboiu Mihail
Adaptative Supramolecular Nanosystems Group, Institut Européen des Membranes, ENSCM/UMII/UMR-CNRS 5635, Pl. Eugène Bataillon, CC 047, 34095 Montpellier Cedex 5, France.
Chem Commun (Camb). 2014 Nov 25;50(91):14086-8. doi: 10.1039/c4cc03866e.
We present herein the compression mechanisms of linear 1,ω-diammonium-alkanes, confined within a molecular cage self-assembled in water. The exact coiling behaviour is determined from atomic resolution X-ray diffraction and shows crenel-like conformations in the compressed states.
我们在此展示了线性1,ω-二铵烷烃的压缩机制，其被限制在水中自组装的分子笼内。精确的盘绕行为由原子分辨率X射线衍射确定，并在压缩状态下呈现出锯齿状构象。
Zotero 插件