A nanoporous Ag(I)-MOF showing unique selective adsorption of benzene among its organic analogues.

作者信息

Cheng Jun-Yan, Wang Peng, Ma Jian-Ping, Liu Qi-Kui, Dong Yu-Bin

机构信息

College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Normal University, Jinan 250014, P. R. China.

出版信息

Chem Commun (Camb). 2014 Nov 18;50(89):13672-5. doi: 10.1039/c4cc03204g.

A stable porous Ag(I)-MOF with new topology is constructed from AgSbF6 and 3,6-bis[2-(4-oxide-quinoxaline)-yl]-4,5-diaza-3,5-octadiene (L). This compound can be a highly selective porous MOF material to effectively separate benzene from its six-membered cyclic organic analogues such as cyclohexane, cyclohexene and o-, m-, p-xylene under ambient conditions in both vapor and liquid phases.