Piroird Keyvan, Lorenceau Elise, Biance Anne-Laure
Institut Lumière Matière, UMR5306 Université Lyon 1-CNRS, Université de Lyon 69622 Villeurbanne, France.
Soft Matter. 2014 Sep 28;10(36):7061-7. doi: 10.1039/c4sm00538d.
The propagation and distribution of oil inside the aqueous network of a foam is investigated in the case where oil can invade the foam without breaking it. The oil is injected into an elementary foam architecture of nine foam films and four vertices obtained by plunging a cubic frame in a foaming solution. The frame is then deformed to trigger a film switching (topological rearrangement named T1) and oil redistribution through this process is reported. Depending on the relative ratio of injected oil and water, different behaviours are observed. For small amounts of oil, a globule is trapped in one single node whereas for large oil volumes, it invades the four nodes of the foam film assembly. In both these cases, a T1 process does not change the oil distribution. However, for intermediate volumes, oil initially trapped in one node is able to propagate to the neighbouring nodes after the T1 process. This important observation shows that topological rearrangements, which naturally occur in foams when they evolve with time or when they flow, do affect the distribution of the third phase that they carry. These different regimes are captured by simple modeling based on the capillary pressure balance inside the foam network. Moreover, in the large-oil-volume limit, a transient situation is evidenced where an oil film is trapped within the freshly formed water film. This oil film modifies the dynamics of the T1 process and can be stable for up to a few minutes. We expect this mechanism to have consequences on the rheological properties of oil-laden foams. Film rupture dynamics is also experimentally captured.
在油能够在不破坏泡沫的情况下侵入泡沫的情形下,研究了油在泡沫水网络内的传播和分布。将油注入由一个立方框架浸入发泡溶液中所得到的、具有九个泡沫膜和四个顶点的基本泡沫结构中。然后使框架变形以引发膜切换(名为T1的拓扑重排),并报告在此过程中的油重新分布情况。根据注入油和水的相对比例,观察到不同的行为。对于少量的油,一个油滴被困在单个节点中,而对于大量的油,它会侵入泡沫膜组件的四个节点。在这两种情况下,T1过程都不会改变油的分布。然而,对于中等量的油,最初被困在一个节点中的油在T1过程之后能够传播到相邻节点。这一重要观察结果表明,当泡沫随时间演化或流动时自然发生的拓扑重排确实会影响它们所携带的第三相的分布。基于泡沫网络内部的毛细管压力平衡,通过简单建模捕捉到了这些不同的状态。此外,在大油量极限情况下,证实了一种瞬态情形,即一层油膜被困在新形成的水膜内。这层油膜改变了T1过程的动力学,并且可以稳定长达几分钟。我们预计这种机制会对含油泡沫的流变特性产生影响。还通过实验捕捉到了膜破裂动力学。