Elmalem Einat, Biedermann Frank, Scherer Maik R J, Koutsioubas Alexandros, Toprakcioglu Chris, Biffi Giulia, Huck Wilhelm T S
Melville Laboratory for Polymer Synthesis, Department of Chemistry, University of Cambridge, Cambridge, CB2 1EW, UK.
Chem Commun (Camb). 2014 Aug 18;50(64):8930-3. doi: 10.1039/c4cc03167a.
Mechanically strong supramolecular hydrogels (up to 98.9% water content) were obtained by the combination of a rigid, fully π-conjugated polymer backbone and zwitterionic side chains. The gels were characterized by SAXS, SEM and rheology measurements and are fluorescent, stimuli responsive (temperature, salts) and bind DNA.
通过刚性的、完全π共轭聚合物主链与两性离子侧链相结合,获得了机械强度高的超分子水凝胶(水含量高达98.9%)。通过小角X射线散射(SAXS)、扫描电子显微镜(SEM)和流变学测量对这些凝胶进行了表征,它们具有荧光性、对刺激有响应(温度、盐)并且能结合DNA。