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可控合成及电纺纳米纤维衍生铁基催化剂的增强电催化性能。

Controllable synthesis and enhanced electrocatalysis of iron-based catalysts derived from electrospun nanofibers.

机构信息

Beijing National Center for Electron Microscopy, Key Laboratory of Advanced Materials (MOE), The State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China.

出版信息

Small. 2014 Oct 29;10(20):4072-9. doi: 10.1002/smll.201401213. Epub 2014 Jul 3.

DOI:10.1002/smll.201401213
PMID:24995876
Abstract

Electrospun carbon nanofibers containing iron and nitrogen are designed to catalyze the oxygen reduction reaction instead of Pt-based catalysts. Their surface morphology is modified finely by using ultralow oxygen flow, and their onset and half-wave potentials are improved to 0.88 V and 0.76 V versus the reversible hydrogen electrode, respectively, approaching those of Pt-based catalysts.

摘要

电纺含铁和氮的碳纳米纤维旨在催化氧还原反应,而不是使用基于 Pt 的催化剂。通过使用超低氧气流量精细地修饰其表面形态,分别将其起始电位和半波电位提高至相对于可逆氢电极的 0.88 V 和 0.76 V,接近基于 Pt 的催化剂的值。

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