Pesticide Toxicology Laboratory, Department of Agricultural Entomology, Tamil Nadu Agricultural University, Coimbatore 641003, Tamil Nadu, India.
Pesticide Toxicology Laboratory, Department of Agricultural Entomology, Tamil Nadu Agricultural University, Coimbatore 641003, Tamil Nadu, India.
Chemosphere. 2014 Sep;111:291-5. doi: 10.1016/j.chemosphere.2014.03.111. Epub 2014 May 13.
The dynamics and residues of deltamethrin in a tea grown in an open field ecosystem were investigated. The quantification was performed using gas chromatography-electron capture detection (GC-ECD) and confirmed by gas chromatograph-mass spectrometry (GC-MS) in selective ion monitoring (SIM) mode. The method was validated using blank samples spiked at three levels and the results showed that recoveries ranged from 87% to 101% with relative standard deviations (RSD) ranging of 0.7-7.1%. The residues of deltamethrin were found to dissipate following first order kinetics with half-life ranging between 3.04 and 3.54d for two different rates of foliar application. The deltamethrin residues are present in the processed tea are not transferred into the tea infusion during the infusion process, since their water solubility is extremely low. These results can be utilized in formulating the spray schedule and safety evaluation on deltamethrin tea crop.
研究了在大田生态系统中种植的茶叶中溴氰菊酯的动态和残留情况。采用气相色谱-电子捕获检测(GC-ECD)进行定量,并通过气相色谱-质谱(GC-MS)在选择离子监测(SIM)模式下进行确证。该方法使用在三个水平下添加的空白样品进行验证,结果表明回收率在 87%至 101%之间,相对标准偏差(RSD)在 0.7%至 7.1%之间。溴氰菊酯的残留量呈一级动力学衰减,两种不同的叶面施用量下的半衰期在 3.04 至 3.54d 之间。加工茶中的溴氰菊酯残留量不会在冲泡过程中转移到茶浸出液中,因为其水溶性极低。这些结果可用于制定溴氰菊酯茶园的喷雾计划和安全评价。