Dollah Sarafhana, Abdulkarim Sabo Muhammad, Ahmad Siti Hajar, Khoramnia Anahita, Ghazali Hasanah Mohd
Department of Food Science, Faculty of Food Science and Technology.
J Oleo Sci. 2014;63(8):811-22. doi: 10.5650/jos.ess13235. Epub 2014 Jul 8.
Blends (30:70, 50:50 and 70:30 w/w) of Moringa oleifera seed oil (MoO) with palm olein (PO), palm stearin (PS), palm kernel oil (PKO) and virgin coconut oil (VCO) were prepared. To determine the physicochemical properties of the blends, the iodine value (IV), saponication value (SV), fatty acid (FA) composition, triacylglycerol (TAG) composition, thermal behaviour (DSC) and solid fat content (SFC) tests were analysed. The incorporation of high oleic acid (81.73%) MoO into the blends resulted in the reduction of palmitic acid content of PO and PS from 36.38% to 17.17% and 54.66% to 14.39% and lauric acid content of PKO and VCO from 50.63% to 17.70% and 51.26% to 26.05% respectively while oleic acid and degree of unsaturation were increased in all blends. Changes in the FA composition and TAG profile have significantly affected the thermal behavior and solid fat content of the oil blends. In MoO/PO blends the melting temperature of MoO decreased while, in MoO/PS, MoO/PKO and MoO/VCO blends, it increased indicating produce of zero-trans harder oil blends without use of partial hydrogenation. The spreadability of PS, PKO and VCO in low temperatures was also increased due to incorporation of MoO. The melting point of PS significantly decreased in MoO/PS blends which proved to be suitable for high oleic bakery shortening and confectionary shortening formulation. The finding appears that blending of MoO with other vegetable oils would enable the initial properties of the oils to be modified or altered and provide functional and nutritional attributes for usage in various food applications, increasing the possibilities for the commercial use of these oils.
制备了辣木籽油(MoO)与棕榈油精(PO)、棕榈硬脂(PS)、棕榈仁油(PKO)和初榨椰子油(VCO)的混合物(质量比分别为30:70、50:50和70:30)。为了测定这些混合物的理化性质,对碘值(IV)、皂化值(SV)、脂肪酸(FA)组成、三酰甘油(TAG)组成、热行为(DSC)和固体脂肪含量(SFC)进行了测试分析。将高油酸(81.73%)的MoO加入混合物中,使PO和PS中的棕榈酸含量分别从36.38%降至17.17%以及从54.66%降至14.39%,PKO和VCO中的月桂酸含量分别从50.63%降至17.70%以及从51.26%降至26.05%,而所有混合物中的油酸含量和不饱和度均有所增加。FA组成和TAG分布的变化显著影响了油混合物的热行为和固体脂肪含量。在MoO/PO混合物中,MoO的熔点降低,而在MoO/PS、MoO/PKO和MoO/VCO混合物中,熔点升高,这表明无需进行部分氢化即可生产零反式的更硬油混合物。由于加入了MoO,PS、PKO和VCO在低温下的延展性也有所提高。在MoO/PS混合物中,PS的熔点显著降低,这被证明适用于高油酸烘焙起酥油和糖果起酥油配方。研究结果表明,将MoO与其他植物油混合能够改变或调整这些油的初始性质,并为各种食品应用提供功能和营养特性,增加了这些油商业化应用的可能性。