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一种新型高能量 Sn-C/Li[Li(0.2)Ni(0.4)/3Co(0.4)/3Mn(1.6/3)]O2 锂离子电池。

A new, high energy Sn-C/Li[Li(0.2)Ni(0.4)/3Co(0.4)/3Mn(1.6/3)]O2 lithium-ion battery.

机构信息

Chemistry Department, Sapienza University of Rome , Piazzale Aldo Moro 5, 00185, Rome, Italy.

出版信息

ACS Appl Mater Interfaces. 2014 Aug 13;6(15):12956-61. doi: 10.1021/am502884y. Epub 2014 Jul 22.

Abstract

In this paper we report a new, high performance lithium-ion battery comprising a nanostructured Sn-C anode and Li[Li0.2Ni0.4/3Co0.4/3Mn1.6/3]O2 (lithium-rich) cathode. This battery shows highly promising long-term cycling stability for up to 500 cycles, excellent rate capability, and a practical energy density, which is expected to be as high as 220 Wh kg(-1) at the packaged cell level. Considering the overall performance of this new chemistry basically related to the optimized structure, morphology, and composition of the utilized active materials as demonstrated by XRD, TEM, and SEM, respectively, the system studied herein is proposed as a suitable candidate for application in the lithium-ion battery field.

摘要

本文报道了一种新型高性能锂离子电池,该电池由纳米结构的 Sn-C 阳极和 Li[Li0.2Ni0.4/3Co0.4/3Mn1.6/3]O2(富锂)阴极组成。该电池具有出色的长期循环稳定性,可达 500 次循环,优异的倍率性能,以及实际能量密度,预计在封装电池水平下高达 220 Wh kg(-1)。考虑到这种新化学物质的整体性能主要与所使用的活性材料的优化结构、形态和组成有关,分别通过 XRD、TEM 和 SEM 进行了证明,因此本文所研究的系统被提议作为锂离子电池领域应用的合适候选者。

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