氮杂环的C-H芳基化：一种使用二芳基碘鎓盐的直接无配体且铜催化的方法。
C-H arylation of azaheterocycles: a direct ligand-free and Cu-catalyzed approach using diaryliodonium salts.
作者信息
Kumar Dalip, Pilania Meenakshi, Arun V, Pooniya Savita
机构信息
Department of Chemistry, Birla Institute of Technology and Science, Pilani 333031, Rajasthan, India.
出版信息
Org Biomol Chem. 2014 Sep 7;12(33):6340-4. doi: 10.1039/c4ob01061b.
PMID:25017573
Abstract
An efficient and high yielding Cu-catalyzed direct C-H arylation of azaheterocycles including oxadiazoles, thiadiazoles, benzoxazoles and benzothiazoles has been achieved by employing easily accessible diaryliodonium salts.
摘要
通过使用易于获得的二芳基碘鎓盐，实现了一种高效且高产率的铜催化含氮杂环（包括恶二唑、噻二唑、苯并恶唑和苯并噻唑）的直接C-H芳基化反应。
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