Barbon Stephanie M, Reinkeluers Pauline A, Price Jacquelyn T, Staroverov Viktor N, Gilroy Joe B
Department of Chemistry and the Centre for Advanced Materials and Biomaterials Research (CAMBR), The University of Western Ontario, 1151 Richmond St. N., London, Ontario, N6A 5B7 (Canada).
Chemistry. 2014 Sep 1;20(36):11340-4. doi: 10.1002/chem.201404297. Epub 2014 Jul 25.
The straightforward synthesis of a series of 3-cyanoformazanate boron difluoride dyes is reported. Phenyl, 4-methoxyphenyl and 4-cyanophenyl N-substituted derivatives were isolated and characterized by single-crystal X-ray crystallography, cyclic voltammetry, and UV/Vis spectroscopy. The compounds were demonstrated to possess tunable, substituent-dependent absorption, emission, and electrochemical properties, which were rationalized through electronic structure calculations.
报道了一系列3-氰基甲脒硼酸二氟化物染料的直接合成方法。分离出了苯基、4-甲氧基苯基和4-氰基苯基N-取代衍生物，并通过单晶X射线晶体学、循环伏安法和紫外/可见光谱对其进行了表征。结果表明，这些化合物具有可调节的、依赖于取代基的吸收、发射和电化学性质，通过电子结构计算对这些性质进行了合理解释。
