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将废弃聚对苯二甲酸乙二醇酯(PET)用作道路铺面材料的方法。

An approach to the usage of polyethylene terephthalate (PET) waste as roadway pavement material.

机构信息

Gazi University, Eng. Fac., Chem. Eng. Depart., 06570 Maltepe-Ankara, Turkey.

Gazi University, Eng. Fac., Civil Eng. Depart., 06570 Maltepe-Ankara, Turkey.

出版信息

J Hazard Mater. 2014 Aug 30;279:302-10. doi: 10.1016/j.jhazmat.2014.07.018. Epub 2014 Jul 18.

Abstract

This study investigates an application area for Polyethylene Terephthalate (PET) bottle waste which has become an environmental problem in recent decades as being a considerable part of the total plastic waste bulk. Two novel additive materials, namely Thin Liquid Polyol PET (TLPP) and Viscous Polyol PET (VPP), were chemically derived from waste PET bottles and used to modify the base asphalt separately for this aim. The effects of TLPP and VPP on the asphalt and hot mix asphalt (HMA) mixture properties were detected through conventional tests (Penetration, Softening Point, Ductility, Marshall Stability, Nicholson Stripping) and Superpave methods (Rotational Viscosity, Dynamic Shear Rheometer (DSR), Bending Beam Rheometer (BBR)). Also, chemical structures were described by Scanning Electron Microscope (SEM) equipped with Energy Dispersive Spectrometer (EDS) and Fourier Transform Infrared (FTIR) techniques. Since TLPP and VPP were determined to improve the low temperature performance and fatigue resistance of the asphalt as well as the Marshall Stability and stripping resistance of the HMA mixtures based on the results of the applied tests, the usage of PET waste as an asphalt roadway pavement material offers an alternative and a beneficial way of disposal of this ecologically hazardous material.

摘要

本研究调查了聚对苯二甲酸乙二醇酯(PET)瓶废物的一个应用领域,近几十年来,由于其成为了塑料废物总量的相当一部分,PET 瓶废物已成为一个环境问题。两种新型添加剂材料,即薄型液体聚对苯二甲酸乙二醇酯(TLPP)和粘性聚对苯二甲酸乙二醇酯(VPP),是从废 PET 瓶中化学衍生而来的,用于分别改性基础沥青。通过常规试验(针入度、软化点、延度、马歇尔稳定度、尼克尔森剥落)和 Superpave 方法(旋转黏度、动态剪切流变仪(DSR)、弯曲梁流变仪(BBR))检测了 TLPP 和 VPP 对沥青和热拌沥青混合料(HMA)混合物性能的影响。此外,还通过扫描电子显微镜(SEM)配备能量色散光谱仪(EDS)和傅里叶变换红外(FTIR)技术描述了化学结构。由于 TLPP 和 VPP 被确定为改善了沥青的低温性能和疲劳性能,以及 HMA 混合物的马歇尔稳定度和抗剥落性能,因此将 PET 废物用作沥青路面材料为这种对生态有害的材料提供了一种替代的、有益的处理方法。

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