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回收废旧印刷电路板的非金属粉末以改善沥青材料性能

Recycling Non-Metallic Powder of Waste Printed Circuit Boards to Improve the Performance of Asphalt Material.

作者信息

Li Sheng, Sun Yu, Fang Shuo, Huang You, Yu Huanan, Ye Ji

机构信息

Key Laboratory of Special Environment Road Engineering of Hunan Province, Changsha University of Science & Technology, Changsha 410114, China.

School of Traffic and Transportation Engineering, Changsha University of Science & Technology, Changsha 410114, China.

出版信息

Materials (Basel). 2022 Jun 12;15(12):4172. doi: 10.3390/ma15124172.

Abstract

Non-metallic fractions (NMFs) from waste printed circuit boards (PCBs) are mostly composed of cured resin and fiber. In this study, NMF material from a PCB was ground into powder and added into matrix asphalt to produce PCB-NMF-modified asphalt. To improve the compatibility of PCB-NMF and asphalt, a compatibilizer consisting of tung oil and glycerol was also developed. The optimum compatibilizer content was determined to be 8% by weight of the PCB-NMF through a series of laboratory tests, including the softening point, penetration, ductility, and softening point difference (SPD). The micro-mechanism of NMF powder-modified asphalt was analyzed through Fourier transform infrared spectroscopy (FTIR) and a scanning electron microscope test (SEM). The performances of PCB-NMF-modified asphalt were evaluated by the dynamic shear rheology (DSR) test and the low-temperature bending beam rheometer (BBR) test. The optimum compatibilizer content was 8% by weight of the NMF powder and the optimum content of NMF powder was determined to be 30% by weight of the asphalt based on a comprehensive evaluation. The results show that PCB-NMF can significantly improve stiffness, rutting resistance, high-temperature stability, and temperature sensitivity of asphalt material at an appropriate content. The BBR tests revealed that PCB-NMF slightly weakened the cracking resistance of asphalt at low temperatures. The SEM test showed that the addition of a compatibilizer can increase the compatibility by making the NMF powder evenly dispersed. The FTIR test results implied that a chemical reaction may not have happened between PCB-NMF, compatibilizer, and the matrix asphalt. Overall, it is a promising and sustainable way to utilize PCB-NMF as a modifier for asphalt material and reduce electronic waste treatment at a low cost.

摘要

废弃印刷电路板(PCBs)中的非金属部分(NMFs)主要由固化树脂和纤维组成。在本研究中,将来自印刷电路板的NMF材料研磨成粉末,并添加到基质沥青中以制备PCB-NMF改性沥青。为了提高PCB-NMF与沥青的相容性,还开发了一种由桐油和甘油组成的增容剂。通过一系列实验室测试,包括软化点、针入度、延度和软化点差(SPD),确定增容剂的最佳含量为PCB-NMF重量的8%。通过傅里叶变换红外光谱(FTIR)和扫描电子显微镜测试(SEM)分析了NMF粉末改性沥青的微观机理。通过动态剪切流变仪(DSR)测试和低温弯曲梁流变仪(BBR)测试对PCB-NMF改性沥青的性能进行了评估。基于综合评估,增容剂的最佳含量为NMF粉末重量的8%,NMF粉末的最佳含量为沥青重量的30%。结果表明,在适当含量下,PCB-NMF可以显著提高沥青材料的刚度、抗车辙能力、高温稳定性和温度敏感性。BBR测试表明,PCB-NMF在低温下略微削弱了沥青的抗裂性。SEM测试表明,添加增容剂可以使NMF粉末均匀分散,从而提高相容性。FTIR测试结果表明,PCB-NMF、增容剂和基质沥青之间可能没有发生化学反应。总体而言,将PCB-NMF用作沥青材料的改性剂并以低成本减少电子废物处理是一种有前景且可持续的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e916/9229897/294c864511af/materials-15-04172-g001.jpg

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