Anomalous one-electron processes in the chemistry of uranium nitrogen multiple bonds.

Novel reaction pathways are illustrated in the synthesis of uranium(IV), uranium(V), and uranium(VI) monoimido complexes. In contrast to the straightforward preparation of U(V)(═NSiMe3)[N(SiMe3)2]3 (1), the synthesis of a uranium(V) tritylimido complex, U(V)(═NCPh3)[N(SiMe3)2]3 (4), from U(III)[N(SiMe3)2]3 and Ph3CN3 was found to proceed through multiple one-electron steps. Whereas the oxidation of 1 with copper(II) salts produced the uranium(VI) monoimido complexes U(VI)(═NSiMe3)X[N(SiMe3)2]3 (X = Cl, Br), the reaction of 4 with CuBr2 undergoes sterically induced reduction to form the uranium(VI) monoimido complex U(VI)(═NCPh3)Br2[N(SiMe3)2]2, demonstrating a striking difference in reactivity based on imido substituent. The facile reduction of compounds 1 and 4 with KC8 allowed for the synthesis of the uranium(IV) monoimido derivatives, K[U(IV)(═NSiMe3)[N(SiMe3)2]3] (1-K) and K[U(IV)(═NCPh3)[N(SiMe3)2]3] (4-K), respectively. In contrast, an analogous uranium(IV) monoimido complex, K[U(IV)(═NPh(F))[N(SiMe3)Ph(F)]], Ph(F) = -pentafluorophenyl (6), was prepared through a loss of N(SiMe3)2Ph(F) concomitant with one-electron oxidation of a uranium(III) center. The uranium(IV) monoimido complexes were found to be reactive toward electrophiles, demonstrating N-C and N-Si single bond formation. One-electron reduction of nitrite provided a route to the uranium(VI) oxo/imido complex, [Ph4P][U(VI)O(═NSiMe3)[N(SiMe3)2]3]. The energetics and electrochemical processes involved in the various oxidation reactions are discussed. Finally, comparison of the U(VI)(═NSiMe3)X[N(SiMe3)2]3, X = Cl, Br, complexes with the previously reported U(VI)OX[N(SiMe3)2]3, X = Cl, Br, complexes suggested that the donor strength of the trimethylsilylimido ligand is comparable to the oxo ligand.