一种用于高效二氧化碳分离的水稳定金属有机框架的组合方法。
A combinatorial approach towards water-stable metal-organic frameworks for highly efficient carbon dioxide separation.
作者信息
Hu Zhigang, Zhang Kang, Zhang Mei, Guo Zhengang, Jiang Jianwen, Zhao Dan
机构信息
Department of Chemical and Biomolecular Engineering, National University of Singapore, 117585 (Singapore), Fax: (+65) 6779-1936 http://www.chbe.nus.edu.sg/faculty/chezhao.
出版信息
ChemSusChem. 2014 Oct;7(10):2791-5. doi: 10.1002/cssc.201402378. Epub 2014 Aug 14.
A library of 20 UiO-66-derived metal-organic frameworks (MOFs) is synthesized in a combinatorial approach involving mixed ligand copolymerization and two post-synthetic modifications (PSMs) in tandem. Mixed ligand co-polymerization of benzene-1,4-dicarboxylic acid (BDC) and sodium 2-sulfoterephthalate (SS-BDC) with zirconium tetrachloride (ZrCl4 ) was used to prepare 5 groups of MOFs with the same UiO-66 topology but differing amounts of sulfate groups. These MOFs exhibit excellent water stabilities in a pH range of 1 to 12, together with high CO2 uptake capacities and selectivities.
通过一种组合方法合成了一个包含20种UiO-66衍生金属有机框架（MOF）的库，该方法涉及混合配体共聚和两个串联的后合成修饰（PSM）。使用对苯二甲酸（BDC）和2-磺基对苯二甲酸钠（SS-BDC）与四氯化锆（ZrCl4）进行混合配体共聚，制备了5组具有相同UiO-66拓扑结构但硫酸根含量不同的MOF。这些MOF在1至12的pH范围内表现出优异的水稳定性，同时具有高二氧化碳吸收能力和选择性。
Zotero 插件