用于染料敏化太阳能电池应用的叶绿素锌材料的合成。
Synthesis of zinc chlorophyll materials for dye-sensitized solar cell applications.
作者信息
Erten-Ela Sule, Vakuliuk Olena, Tarnowska Anna, Ocakoglu Kasim, Gryko Daniel T
机构信息
Solar Energy Institute, Ege University, Bornova 35100, Izmir, Turkey.
Institute of Organic Chemistry of the Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland.
出版信息
Spectrochim Acta A Mol Biomol Spectrosc. 2015 Jan 25;135:676-82. doi: 10.1016/j.saa.2014.07.026. Epub 2014 Aug 1.
To design sensitizers for dye sensitized solar cells (DSSCs), a series of zinc chlorins with different substituents were synthesized. Novel zinc methyl 3-devinyl-3-hydroxymethyl-20-phenylacetylenylpyropheophorbide-a (ZnChl-1), zinc methyl 20-bromo-3-devinyl-3-hydroxymethylpyropheophorbide-a (ZnChl-2), zinc methyl 3-devinyl-3-hydroxymethyl-pyropheophorbide-a (ZnChl-3), zinc propyl 3-devinyl-3-hydroxymethyl-pyropheophorbide-a (ZnChl-4) were synthesized and their photovoltaic performances were evaluated in dye-sensitized solar cells. Photoelectrodes with a 7 μm thick nanoporous layer and a 5 μm thick light-scattering layer were used to fabricate dye sensitized solar cells. The best efficiency was obtained with ZnChl-2 sensitizer. ZnChl-2 gave a Jsc of 3.5 mA/cm(2), Voc of 412 mV, FF of 0.56 and an overall conversion efficiency of 0.81 at full sun (1000 W m(-2)).
为了设计用于染料敏化太阳能电池（DSSC）的敏化剂，合成了一系列具有不同取代基的二氢卟吩锌。合成了新型的甲基 3-脱乙烯基-3-羟甲基-20-苯基乙炔基焦脱镁叶绿酸-a 锌（ZnChl-1）、甲基 20-溴-3-脱乙烯基-3-羟甲基焦脱镁叶绿酸-a 锌（ZnChl-2）、甲基 3-脱乙烯基-3-羟甲基焦脱镁叶绿酸-a 锌（ZnChl-3）、丙基 3-脱乙烯基-3-羟甲基焦脱镁叶绿酸-a 锌（ZnChl-4），并在染料敏化太阳能电池中评估了它们的光伏性能。使用具有 7μm 厚纳米多孔层和 5μm 厚光散射层的光电极来制备染料敏化太阳能电池。使用 ZnChl-2 敏化剂时获得了最佳效率。在全日照（1000 W m(-2)）下，ZnChl-2 的短路电流密度（Jsc）为 3.5 mA/cm²，开路电压（Voc）为 412 mV，填充因子（FF）为 0.56，总转换效率为 0.81。
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