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两种相位匹配性不同的钒氧化物氟化物材料的合成。

Syntheses of two vanadium oxide-fluoride materials that differ in phase matchability.

作者信息

Donakowski Martin D, Gautier Romain, Lu Hongcheng, Tran T Thao, Cantwell Jacqueline R, Halasyamani P Shiv, Poeppelmeier Kenneth R

机构信息

Department of Chemistry, Northwestern University , 2145 Sheridan Road, Evanston, Illinois 60208-3113, United States.

出版信息

Inorg Chem. 2015 Feb 2;54(3):765-72. doi: 10.1021/ic501486x. Epub 2014 Aug 19.

DOI:10.1021/ic501486x
PMID:25137441
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4317054/
Abstract

The syntheses of two noncentrosymmetric (NCS) vanadium oxide-fluoride compounds that originate from the same synthetic reagent concentrations are presented. Hydrothermal and low-temperature syntheses allow the isolation of metastable products that may form new phases (or decompose) upon heating and allow creation of chemically similar but structurally different materials. NCS materials synthesis has been a long-standing goal in inorganic chemistry: in this article, we compare two chemically similar NCS inorganic materials, NaVOF(4)(H(2)O) (I) and NaVO(2-x)F(2+x) (II; x = 1/3). These materials originate from the same, identical reagent mixtures but are synthesized at different temperatures: 100 °C and 150 °C, respectively. Compound I crystallizes in Pna2(1): a = 9.9595(4) Å, b = 9.4423(3) Å, and c = 4.8186(2) Å. Compound II crystallizes in P2(1): a = 6.3742(3) Å, b = 3.5963(2) Å, c = 14.3641(7) Å, and β = 110.787(3)°. Both materials display second-harmonic-generation activity; however, compound I is type 1 non-phase-matchable, whereas compound II is type 1 phase-matchable.

摘要

本文介绍了两种由相同合成试剂浓度制备的非中心对称（NCS）钒氧化物氟化物化合物的合成。水热合成和低温合成能够分离出亚稳产物，这些产物在加热时可能会形成新相（或分解），并能制备出化学性质相似但结构不同的材料。NCS材料的合成一直是无机化学领域长期追求的目标：在本文中，我们比较了两种化学性质相似的NCS无机材料，NaVOF₄(H₂O)（I）和NaVO₂₋ₓF₂₊ₓ（II；x = 1/3）。这些材料源自相同的试剂混合物，但合成温度不同，分别为100℃和150℃。化合物I以Pna2₁空间群结晶：a = 9.9595(4) Å，b = 9.4423(3) Å，c = 4.8186(2) Å。化合物II以P2₁空间群结晶：a = 6.3742(3) Å，b = 3.5963(2) Å，c = 14.3641(7) Å，β = 110.787(3)°。两种材料均表现出二次谐波产生活性；然而，化合物I是1型非相位匹配的，而化合物II是1型相位匹配的。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/ef881f51eb04/ic-2014-01486x_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/de8e491a9e7c/ic-2014-01486x_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/0c1e3180f646/ic-2014-01486x_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/f33f19c08162/ic-2014-01486x_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/415df34b89ef/ic-2014-01486x_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/ef881f51eb04/ic-2014-01486x_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/de8e491a9e7c/ic-2014-01486x_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/0c1e3180f646/ic-2014-01486x_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/f33f19c08162/ic-2014-01486x_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/415df34b89ef/ic-2014-01486x_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1011/4317054/ef881f51eb04/ic-2014-01486x_0006.jpg

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2
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Phys Rev Lett. 2014 Jan 10;112(1):017207. doi: 10.1103/PhysRevLett.112.017207.
3
Polar alignment of Λ-shaped basic building units within transition metal oxide fluoride materials.过渡金属氟氧化物材料中 Λ 型基本结构单元的极轴取向。
Inorg Chem. 2014 Jan 6;53(1):221-8. doi: 10.1021/ic402177j. Epub 2013 Dec 12.
4
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J Am Chem Soc. 2013 Aug 14;135(32):11942-50. doi: 10.1021/ja4050604. Epub 2013 Aug 5.
5
AgNa(VO2F2)2: a trioxovanadium fluoride with unconventional electrochemical properties.AgNa(VO2F2)2：一种具有非传统电化学性能的三氧化二氟合钒酸钠。
J Am Chem Soc. 2013 Jul 3;135(26):9898-906. doi: 10.1021/ja404189t. Epub 2013 Jun 24.
6
Designing a deep-ultraviolet nonlinear optical material with a large second harmonic generation response.设计具有大二次谐波响应的深紫外非线性光学材料。
J Am Chem Soc. 2013 Mar 20;135(11):4215-8. doi: 10.1021/ja400500m. Epub 2013 Mar 12.
7
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Inorg Chem. 2012 Sep 3;51(17):9192-9. doi: 10.1021/ic3001834. Epub 2012 Apr 23.
8
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9
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10
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J Am Chem Soc. 2012 Feb 8;134(5):2621-5. doi: 10.1021/ja208587e. Epub 2012 Jan 30.