锰（II）/氧气促进的乙烯基异腈与硼酸的氧化环化反应：多取代异喹啉的合成
Mn(II)/O2-promoted oxidative annulation of vinyl isocyanides with boronic acids: synthesis of multi-substituted isoquinolines.
作者信息
Wang Hao, Yu Yang, Hong Xiaohu, Xu Bin
机构信息
Department of Chemistry, Innovative Drug Research Center, Shanghai University, Shanghai 200444, China.
出版信息
Chem Commun (Camb). 2014 Nov 14;50(88):13485-8. doi: 10.1039/c4cc06427e.
PMID:25236810
Abstract
An efficient manganese(II)/O2-promoted oxidative radical cascade reaction was developed for the modular synthesis of multi-substituted isoquinolines from easily accessible vinyl isocyanides and boronic acids.
摘要
开发了一种高效的锰（II）/氧气促进的氧化自由基级联反应，用于从易于获得的乙烯基异氰化物和硼酸模块化合成多取代异喹啉。
相似文献
1
Mn(II)/O2-promoted oxidative annulation of vinyl isocyanides with boronic acids: synthesis of multi-substituted isoquinolines.
Chem Commun (Camb). 2014 Nov 14;50(88):13485-8. doi: 10.1039/c4cc06427e.
2
Cu(II) catalyzed oxidation-[3+2] cycloaddition-aromatization cascade: efficient synthesis of pyrrolo [2, 1-a] isoquinolines.
Chem Commun (Camb). 2011 Jan 21;47(3):1036-8. doi: 10.1039/c0cc03186k. Epub 2010 Nov 12.
3
Suzuki cross-coupling/reductive debenzyloxycarbonylation sequence for the syntheses of [c]annulated isoquinolines: application for the syntheses of pancratistatin-like isoquinolines.
J Org Chem. 2008 Oct 17;73(20):8128-31. doi: 10.1021/jo801761f. Epub 2008 Sep 23.
4
Palladium-catalyzed intermolecular oxidative cyclization of N-aryl enamines with isocyanides through double sp(2) C-H bonds cleavage: facile synthesis of 4-aminoquinoline derivatives.
Org Biomol Chem. 2015 Apr 28;13(16):4657-60. doi: 10.1039/c5ob00329f.
5
Synthesis of oxazoles by silver catalysed oxidative decarboxylation-cyclization of α-oxocarboxylates and isocyanides.
Chem Commun (Camb). 2015 Jul 4;51(52):10524-7. doi: 10.1039/c5cc02253c.
6
Suzuki-Miyaura coupling of heteroaryl boronic acids and vinyl chlorides.
Chem Commun (Camb). 2012 Jan 7;48(2):203-5. doi: 10.1039/c1cc15990a. Epub 2011 Nov 14.
7
Synthesis of isoquinolines via visible light-promoted insertion of vinyl isocyanides with diaryliodonium salts.
Chem Commun (Camb). 2014 Jun 11;50(46):6164-7. doi: 10.1039/c4cc01122h.
8
Chemo- and regioselective assembly of polysubstituted pyridines and isoquinolines from isocyanides, arynes, and terminal alkynes.
J Org Chem. 2012 Apr 20;77(8):3754-65. doi: 10.1021/jo300072x. Epub 2012 Apr 4.
9
Rh-catalyzed sequential oxidative C-H activation/annulation with geminal-substituted vinyl acetates to access isoquinolines.
Chem Commun (Camb). 2015 Sep 4;51(68):13327-9. doi: 10.1039/c5cc04708k.
10
Isoquinoline synthesis by heterocyclization of tosylmethyl isocyanide derivatives: total synthesis of mansouramycin B.
Org Lett. 2015 Jan 2;17(1):78-81. doi: 10.1021/ol5032624. Epub 2014 Dec 18.
Zotero 插件