College of Environmental Science and Engineering, Nankai University, Tianjin 300071, PR China.
College of Environmental Science and Engineering, Nankai University, Tianjin 300071, PR China.
Carbohydr Polym. 2014 Nov 26;113:1-8. doi: 10.1016/j.carbpol.2014.06.067. Epub 2014 Jul 1.
In this study, alumina-doped MgO was produced as a solid alkali for lignocellulose pretreatment. Pretreatment with alumina-doped MgO disrupted the lignocellulose structure and significantly reduced the lignin content of the Z. japonica. After pretreatment, Z. japonica showed significant solubility in 1-allyl-3-methylimidazolium chloride (AMIMCl). The similar high solubility of pretreated Z. japonica samples by original alumina-doped MgO and used alumina-doped MgO also proved that alumina-doped MgO had strong stability, which can be recycled and used repeatedly. The regenerated cellulose was similar to microcrystalline cellulose according to FTIR and NMR analyses. Compared to microcrystalline cellulose, only the crystallinity of the regenerated cellulose decreased.
本研究采用氧化铝掺杂氧化镁作为固体碱预处理木质纤维素。氧化铝掺杂氧化镁预处理破坏了木质纤维素的结构,显著降低了黄麻的木质素含量。预处理后,黄麻在 1-烯丙基-3-甲基咪唑氯盐(AMIMCl)中具有显著的溶解性。原氧化铝掺杂氧化镁和用过的氧化铝掺杂氧化镁预处理的黄麻样品具有相似的高溶解度也证明了氧化铝掺杂氧化镁具有很强的稳定性,可以回收和重复使用。再生纤维素的傅里叶变换红外光谱(FTIR)和核磁共振(NMR)分析表明,其类似于微晶纤维素。与微晶纤维素相比,只有再生纤维素的结晶度降低。