Chen Peng-Fei, Tian Di, Qiao Shu-Jun, Yang Guang
Guang Pu Xue Yu Guang Pu Fen Xi. 2014 Jul;34(7):1969-72.
Spectrum peak detection in the laser-induced breakdown spectroscopy (LIBS) is an essential step, but the presence of background and noise seriously disturb the accuracy of peak position. The present paper proposed a method applied to automatic peak detection for LIBS spectrum in order to enhance the ability of overlapping peaks searching and adaptivity. We introduced the ridge peak detection method based on continuous wavelet transform to LIBS, and discussed the choice of the mother wavelet and optimized the scale factor and the shift factor. This method also improved the ridge peak detection method with a correcting ridge method. The experimental results show that compared with other peak detection methods (the direct comparison method, derivative method and ridge peak search method), our method had a significant advantage on the ability to distinguish overlapping peaks and the precision of peak detection, and could be be applied to data processing in LIBS.
激光诱导击穿光谱(LIBS)中的光谱峰值检测是一个关键步骤,但背景和噪声的存在严重干扰了峰值位置的准确性。本文提出了一种应用于LIBS光谱自动峰值检测的方法,以增强重叠峰搜索能力和适应性。我们将基于连续小波变换的脊峰检测方法引入到LIBS中,并讨论了母小波的选择,优化了尺度因子和偏移因子。该方法还采用校正脊线法对脊峰检测方法进行了改进。实验结果表明,与其他峰值检测方法(直接比较法、导数法和脊峰搜索法)相比,我们的方法在区分重叠峰的能力和峰值检测精度方面具有显著优势,可应用于LIBS的数据处理。