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在真空反应器中对中国褐煤和生物质进行共热解。

Co-pyrolysis of Chinese lignite and biomass in a vacuum reactor.

机构信息

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China.

School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, PR China.

出版信息

Bioresour Technol. 2014 Dec;173:1-5. doi: 10.1016/j.biortech.2014.09.073. Epub 2014 Sep 22.

Abstract

A vacuum fixed bed reactor was applied to pyrolyze lignite, biomass (rice husk) and their blend with high temperature (900 °C) and low heating rate (10 °C/min). Pyrolytic products were kept in the vacuum reactor during the whole pyrolysis process, guaranteeing a long contact time (more than 2 h) for their interactions. Remarkable synergetic effects were observed. Addition of biomass obviously influenced the tar and char yields, gas volume yield, gas composition, char structure and tar composition during co-pyrolysis. It was highly possible that char gasification, gaseous phase interactions, and secondary tar cracking were facilitated when lignite and biomass were co-pyrolyzed.

摘要

应用真空固定床反应器,在高温(900°C)和低加热速率(10°C/min)下对褐煤、生物质(稻壳)及其混合物进行热解。在整个热解过程中,热解产物保留在真空反应器中,以保证其长时间接触(超过 2 小时),从而促进相互作用。观察到显著的协同效应。在共热解过程中,生物质的添加明显影响焦油和半焦产率、气体体积产率、气体组成、半焦结构和焦油组成。当褐煤和生物质共热解时,很可能促进了半焦气化、气相相互作用和二次焦油裂解。

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