Pham Tony, Forrest Katherine A, Georgiev Peter A, Lohstroh Wiebke, Xue Dong-Xu, Hogan Adam, Eddaoudi Mohamed, Space Brian, Eckert Juergen
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue, CHE205, Tampa, FL 33620, USA.
Chem Commun (Camb). 2014 Nov 25;50(91):14109-12. doi: 10.1039/c4cc05987e.
A combined inelastic neutron scattering (INS) and theoretical study of H2 sorption in Y-FTZB, a recently reported metal-organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H2. This rotational barrier for H2 is the highest yet of reported MOF materials based on physisorption.
一项结合非弹性中子散射（INS）和理论研究的关于Y - FTZB（一种最近报道的具有fcu拓扑结构的金属有机框架（MOF））中氢气吸附的研究表明，该MOF中最强的结合位点对吸附的氢气产生了较高的旋转势垒。基于物理吸附的MOF材料中，这种氢气的旋转势垒是迄今所报道的最高的。
