The first five-membered-heterocycle-fused subphthalocyanine analogues: chiral tri(benzo[b]thiopheno)subporphyrazines.
作者信息
Shang Hong, Zhao Luyang, Qi Dongdong, Chen Chao, Jiang Jianzhuang
机构信息
Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing, 10083 (P.R. China).
出版信息
Chemistry. 2014 Dec 1;20(49):16266-72. doi: 10.1002/chem.201404164. Epub 2014 Oct 14.
PMID:25314028
Abstract
Two tri(benzo[b]thiopheno)subporphyrazine regioisomers with C3 and C1 molecular symmetry have been isolated from the cyclotrimerization of benzo[b]thiophene-2,3-dicarbonitrile as the first five-membered-heterocycle-fused subphthalocyanine analogues. Optical resolution of both regioisomers was achieved by using a chiral HPLC technique, affording the first chiral subphthalocyanine analogues.
摘要
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