吲哚不对称功能化策略：最新进展。

Strategies for the asymmetric functionalization of indoles: an update.

机构信息

Dipartimento di Chimica e Tecnologie Chimiche, Università della Calabria, Ponte Bucci, Cubo 12/C I-87036 Arcavacata di Rende (Cs), Italy.

出版信息

Chem Soc Rev. 2015 Feb 7;44(3):742-78. doi: 10.1039/c4cs00209a.

DOI:10.1039/c4cs00209a

PMID:25316161

Abstract

During the past four years, the research of new synthetic methodologies for the rapid construction of enantiomerically pure substituted indole has had a fruitful and important growth. This research line continues to produce stunning arrays of enantioselective technologies either metal or organocatalyzed. Thus, an update of our previous review (Chem. Soc. Rev., 2010, 39, 4449-4465) has become necessary and this critical review documents the literature on this topic, until the end of 2013.

摘要

在过去的四年中，用于快速构建对映纯取代吲哚的新综合方法的研究取得了丰硕而重要的发展。这条研究路线继续产生令人惊叹的各种对映选择性技术，无论是金属催化还是有机催化。因此，我们之前的综述（Chem. Soc. Rev.，2010，39，4449-4465）需要更新，这篇批判性综述记录了截至 2013 年底关于该主题的文献。