两种羧乙基锡官能化的多金属氧酸盐，用于组装在碳纳米管上作为染料敏化太阳能电池中的高效对电极材料。
Two carboxyethyltin functionalized polyoxometalates for assembly on carbon nanotubes as efficient counter electrode materials in dye-sensitized solar cells.
作者信息
Sang Xiao-Jing, Li Jian-Sheng, Zhang Lan-Cui, Zhu Zai-Ming, Chen Wei-Lin, Li Yang-Guang, Su Zhong-Min, Wang En-Bo
机构信息
Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China.
出版信息
Chem Commun (Camb). 2014 Dec 4;50(93):14678-81. doi: 10.1039/c4cc06211f.
Two novel open-chain carboxyethyltin decorated sandwich-type germanotungstates have been successfully synthesized. They could markedly increase the electrocatalytic activity of single-walled carbon nanotubes toward triiodide reduction when assembled into composite electrodes, which have shown a conversion efficiency of 6.32% that is comparable to that of Pt electrodes (6.29%) when used as counter electrodes in dye-sensitized solar cells.
两种新型的开链羧乙基锡修饰的夹心型锗钨酸盐已成功合成。当组装成复合电极时，它们能显著提高单壁碳纳米管对三碘化物还原的电催化活性，在染料敏化太阳能电池中用作对电极时，其转换效率为6.32%，与铂电极（6.29%）相当。
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