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基于两个类似的吡啶基取代咪唑-4,5-二羧酸酯配体的十八核大环和九核碗状结构。

Octadecanuclear macrocycles and nonanuclear bowl-shaped structures based on two analogous pyridyl-substituted imidazole-4,5-dicarboxylate ligands.

机构信息

Shanghai Key Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University , Shanghai 200433, P. R. China.

出版信息

J Am Chem Soc. 2014 Nov 5;136(44):15521-4. doi: 10.1021/ja5096914. Epub 2014 Oct 27.

DOI:10.1021/ja5096914
PMID:25329984
Abstract

Two types of unprecedented CpRh-based (Cp = η(5)-C5Me5) complexes, two octadecanuclear macrocycles, and a nonanuclear bowl-shaped complex have been synthesized from two analogous pyridyl-functionalized imidazole-4,5-dicarboxylate ligands, 2-(pyridin-4-yl)-1H-imidazole-4,5-dicarboxylate ligand and 2-(pyridin-3-yl)-1H-imidazole-4,5-dicarboxylate ligand, respectively.

摘要

两种前所未有的基于 CpRh 的（Cp = η(5)-C5Me5）配合物，两种十八核大环和一种九核碗状配合物，分别由两种类似的吡啶基功能化咪唑-4,5-二羧酸酯配体 2-(吡啶-4-基)-1H-咪唑-4,5-二羧酸酯配体和 2-(吡啶-3-基)-1H-咪唑-4,5-二羧酸酯配体合成得到。

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