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动力学控制合成具有增强电催化活性的 PdNi 双金属多孔纳米结构。

Kinetically controlled synthesis of PdNi bimetallic porous nanostructures with enhanced electrocatalytic activity.

机构信息

Physical Chemistry, TU Dresden, Bergstrasse 66b, 01062, Dresden, Germany.

出版信息

Small. 2015 Mar 25;11(12):1430-4. doi: 10.1002/smll.201401432. Epub 2014 Oct 21.

DOI:10.1002/smll.201401432
PMID:25336342
Abstract

A class of 3D PdNi bimetallic nano-materials with porous nanostructures is synthesized using a facile and versatile approach at room temperature. Due to their porous nanostructures, their clean surfaces, as well as the synergistic effect between their compositions, the as-prepared PdNi exhibit greatly enhanced activity and stability towards methanol electrooxidation in an alkaline medium, holding great promise in fuel cells.

摘要

一类具有多孔纳米结构的 3D PdNi 双金属纳米材料是通过一种简便通用的室温方法合成的。由于其具有多孔纳米结构、洁净的表面以及组成之间的协同效应,所制备的 PdNi 对碱性介质中甲醇的电氧化表现出极大的增强的活性和稳定性,在燃料电池中具有很大的应用前景。

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