Department of Chemistry, The University of Chicago, 929 E. 57th Street, Chicago, IL, 60637, USA.
Adv Mater. 2014 Dec 17;26(47):7993-7. doi: 10.1002/adma.201403428. Epub 2014 Oct 27.
An innovative wet-treatment with Na2 S transforms two indium metal-organic frameworks (MOFs) into a series of porous inorganic sorbents. These MOF-templated materials display remarkable affinity for heavy metals with saturation occurring in less than 1 h. The saturation capacity for Hg(II) exceeds 2 g g(-1) , more than doubling the best thiol-functionalized sorbents in the literature.
一种创新的 Na2S 湿法处理将两种铟金属有机骨架(MOF)转化为一系列多孔无机吸附剂。这些 MOF 模板材料对重金属表现出显著的亲和力,饱和时间不到 1 小时。Hg(II)的饱和容量超过 2 g g(-1),是文献中最好的硫醇功能化吸附剂的两倍多。