Aziz Jessy, Messaoudi Samir, Alami Mouad, Hamze Abdallah
Univ Paris Sud, CNRS, BioCIS UMR 8076, Laboratoire de Chimie Thérapeutique, Equipe Labellisée Ligue Contre le Cancer, LabEx LERMIT, Faculté de Pharmacie, 5 rue J-B Clément, Châtenay-Malabry, F-92296, France.
Org Biomol Chem. 2014 Dec 28;12(48):9743-59. doi: 10.1039/c4ob01727g.
Sulfinic acids and their salts have recently emerged as versatile coupling partners to efficiently access a wide variety of hetero- and carbocyclic compounds, under relatively mild conditions. Their growing importance is attributable to their dual capacity for acting as nucleophilic or electrophilic reagents. This report summarizes recent advances in the preparation and use of sulfinates in organic synthesis.
亚磺酸及其盐类最近已成为通用的偶联伙伴，能够在相对温和的条件下高效合成多种杂环和碳环化合物。它们日益增长的重要性归因于其兼具亲核试剂或亲电试剂的双重能力。本报告总结了亚磺酸盐在有机合成中的制备及应用方面的最新进展。
