在可见光照射下，BiVO₄上胺类光催化有氧氧化生成亚胺。
Photocatalytic aerobic oxidation of amines to imines on BiVO4 under visible light irradiation.
作者信息
Yuan Bo, Chong Ruifeng, Zhang Bao, Li Jun, Liu Yan, Li Can
机构信息
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
出版信息
Chem Commun (Camb). 2014 Dec 21;50(98):15593-6. doi: 10.1039/c4cc07097f. Epub 2014 Oct 31.
PMID:25360458
Abstract
BiVO4 was found to be an efficient photocatalyst under visible light irradiation for selective oxidation of amines to imines with high activity (99% conversion) and selectivity (up to 99%) using oxygen as an oxidant.
摘要
研究发现，BiVO4在可见光照射下是一种高效的光催化剂，以氧气作为氧化剂，可将胺选择性氧化为亚胺，具有高活性（转化率99%）和高选择性（高达99%）。
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