Xu Xiao-Juan
School of Chemistry and Chemical Engineering, Yancheng Teachers University, Yancheng 224002, People's Republic of China.
Acta Crystallogr C Struct Chem. 2014 Nov;70(Pt 11):1033-5. doi: 10.1107/S2053229614022177. Epub 2014 Oct 11.
In the title one-dimensional Zn(II) coordination polymer, [Zn(C10H8O4)(0.5)Cl(C12H12N6)]n, the asymmetric unit consists of a Zn(II) cation, a 1,3-bis[(1H-1,2,4-triazol-1-yl)methyl]benzene ligand and half of a fully deprotonated centrosymmetric 1,4-phenylenediacetic acid ligand. The crystal structure shows a one-dimensional rotaxane-like structure. This coordination polymer is reinforced by C-H···O and C-H···Cl hydrogen bonds and π-π interactions.
在标题化合物一维锌（II）配位聚合物[Zn(C₁₀H₈O₄)(0.5)Cl(C₁₂H₁₂N₆)]ₙ中，不对称单元由一个锌（II）阳离子、一个1,3-双[(1H-1,2,4-三唑-1-基)甲基]苯配体和一个中心对称的完全去质子化的1,4-苯二甲酸配体的一半组成。晶体结构显示出一维轮烷状结构。该配位聚合物通过C-H···O和C-H···Cl氢键以及π-π相互作用得到加强。
