Biology and Biotechnology Division, Physical and Life Sciences Directorate, Lawrence Livermore National Laboratory , Livermore, California 94550, United States.
Nano Lett. 2014 Dec 10;14(12):7051-6. doi: 10.1021/nl5034446. Epub 2014 Nov 5.
We report the measurements of transport of ions and uncharged species through carbon nanotube (CNT) porins--short segments of CNTs inserted into a lipid bilayer membrane. Rejection characteristics of the CNT porins are governed by size exclusion for the uncharged species. In contrast, rejection of ionic species is governed by the electrostatic repulsion and Donnan membrane equilibrium. Permeability of monovalent cations follows the general trend in the hydrated ion size, except in the case of Cs(+) ions.
我们报告了离子和不带电物质通过碳纳米管(CNT)孔蛋白的传输测量——短段 CNT 插入脂质双层膜中。不带电物质的 CNT 孔蛋白的排斥特性由大小排除决定。相比之下,离子物质的排斥由静电排斥和唐南膜平衡决定。单价阳离子的渗透率遵循水合离子大小的一般趋势,除了 Cs(+)离子的情况。