Dai Caili, Wang Kai, Liu Yifei, Fang Jichao, Zhao Mingwei
China University of Petroleum (East China), Qingdao, Shandong, 266580, People's Republic of China.
China University of Petroleum (East China), Qingdao, Shandong, 266580, People's Republic of China; China National Offshore Oil Corporation Research Institute, Beijing, 100028, People's Republic of China.
PLoS One. 2014 Nov 19;9(11):e113723. doi: 10.1371/journal.pone.0113723. eCollection 2014.
An investigation was conducted to study the reutilization of clear fracturing flowback fluids composed of viscoelastic surfactants (VES) with additives in surfactant flooding, making the process more efficient and cost-effective. The clear fracturing flowback fluids were used as surfactant flooding system with the addition of α-olefin sulfonate (AOS) for enhanced oil recovery (EOR). The interfacial activity, emulsification activity and oil recovery capability of the recycling system were studied. The interfacial tension (IFT) between recycling system and oil can be reduced by 2 orders of magnitude to 10(-3) mN/m, which satisfies the basic demand of surfactant flooding. The oil can be emulsified and dispersed more easily due to the synergetic effect of VES and AOS. The oil-wet surface of quartz can be easily converted to water-wet through adsorption of surfactants (VES/AOS) on the surface. Thirteen core plug flooding tests were conducted to investigate the effects of AOS concentrations, slug sizes and slug types of the recycling system on the incremental oil recovery. The investigations prove that reclaiming clear fracturing flowback fluids after fracturing operation and reuse it in surfactant flooding might have less impact on environment and be more economical.
开展了一项研究,以探讨由含添加剂的粘弹性表面活性剂(VES)组成的清洁压裂返排液在表面活性剂驱油中的再利用,从而提高该过程的效率和成本效益。将清洁压裂返排液用作表面活性剂驱油体系,并添加α-烯烃磺酸盐(AOS)以提高采收率(EOR)。研究了该循环利用体系的界面活性、乳化活性和采油能力。循环利用体系与油之间的界面张力(IFT)可降低2个数量级至10^(-3) mN/m,满足表面活性剂驱油的基本要求。由于VES和AOS的协同作用,油更容易被乳化和分散。通过表面活性剂(VES/AOS)在石英表面的吸附,石英的油湿表面可轻松转变为水湿表面。进行了13次岩心驱替试验,以研究循环利用体系中AOS浓度、段塞大小和段塞类型对增油采收率的影响。研究证明,压裂作业后回收清洁压裂返排液并将其重新用于表面活性剂驱油可能对环境影响较小且更经济。