关于与铂（II）形成的氢键的本质——哪种相互作用可以预测其强度？
On the nature of hydrogen bonds to platinum(II)--which interaction can predict their strength?
作者信息
Sánchez-de-Armas Rocío, Ahlquist Mårten S G
机构信息
Division of Theoretical Chemistry & Biology School of Biotechnology, Royal Institute of Technology, S-10691, Stockholm, Sweden.
出版信息
Phys Chem Chem Phys. 2015 Jan 14;17(2):812-6. doi: 10.1039/c4cp04657a. Epub 2014 Nov 21.
PMID:25412734
Abstract
The interaction between hydrogen bond donors and platinum has been analysed. Our results point to an interaction that can be entirely predicted from the dz(2) orbital energy of the platinum centre indicating strong charge transfer, with significant dispersion contribution to the bonding, very different from classical hydrogen bonds.
摘要
已对氢键供体与铂之间的相互作用进行了分析。我们的结果表明，这种相互作用可以完全根据铂中心的dz(2)轨道能量预测，这表明存在强烈的电荷转移，且对键合有显著的色散贡献，这与经典氢键非常不同。
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