Yang Wei, Wang Shan, Zhang Qian, Liu Qun, Xu Xianxiu
Department of Chemistry, Northeast Normal University, Changchun 130024, China.
Chem Commun (Camb). 2015 Jan 14;51(4):661-4. doi: 10.1039/c4cc08260e.
An efficient Rh(III)-catalyzed C-H bond arylation with phenol derivatives was developed for the direct and sustainable synthesis of dibenzo[b,d]pyran-6-ones and benzo[d]naphtho[1,2-b]pyran-6-ones. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent chemoselectivity.
开发了一种高效的铑（III）催化的苯酚衍生物与碳氢键芳基化反应，用于直接且可持续地合成二苯并[b,d]吡喃-6-酮和苯并[d]萘并[1,2-b]吡喃-6-酮。该反应具有良好的底物范围和出色的官能团兼容性，能以良好的产率和优异的化学选择性得到产物。
