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基于咪唑钴骨架材料的高选择性和高灵敏度三甲胺气体传感器。

Highly selective and sensitive trimethylamine gas sensor based on cobalt imidazolate framework material.

作者信息

Chen Er-Xia, Fu Hong-Ru, Lin Rui, Tan Yan-Xi, Zhang Jian

机构信息

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou, Fujian 350002, People's Republic of China.

出版信息

ACS Appl Mater Interfaces. 2014 Dec 24;6(24):22871-5. doi: 10.1021/am5071317. Epub 2014 Dec 3.

Abstract

A cobalt imidazolate (im) framework material [Co(im)2]n was employed to use as a trimethylamine (TMA) gas sensor and the [Co(im)2]n sensor can be easily fabricated by using Ag-Pd interdigitated electrodes. Gas sensing measurement indicated that the [Co(im)2]n sensor shows excellent selectivity, high gas response and a low detection limit level of 2 ppm to TMA at 75 °C. The good selectivity and high response to TMA of the sensor based on [Co(im)2]n may be attributed to the weak interaction between the TMA molecules and the [Co(im)2]n framework. That may provide an ideal candidate for detecting freshness of fish and seafood.

摘要

一种咪唑钴(im)框架材料[Co(im)₂]ₙ被用作三甲胺(TMA)气体传感器,并且[Co(im)₂]ₙ传感器可以通过使用银钯叉指电极轻松制备。气敏测量表明,[Co(im)₂]ₙ传感器表现出优异的选择性、高气体响应以及在75℃下对TMA的低检测限水平为2 ppm。基于[Co(im)₂]ₙ的传感器对TMA具有良好的选择性和高响应性,这可能归因于TMA分子与[Co(im)₂]ₙ框架之间的弱相互作用。这可能为检测鱼类和海鲜的新鲜度提供理想的候选材料。

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