焦磷酸盐和二磷酸腺苷（ADP）的三氨一 aquocobalt(III) 配合物。
Triamminemonoaquocobalt(III) complexes of pyrophosphate and adenosine diphosphate (ADP).
作者信息
Speckhard D C, Knight W B, Rawlings J, Cleland W W
机构信息
Department of Biochemistry, University of Wisconsin, Madison 53706.
出版信息
J Inorg Biochem. 1989 Jun;36(2):99-106. doi: 10.1016/0162-0134(89)80017-0.
Cobalt(III)H2O(NH3)3 pyrophosphate has been shown by proton and 31P nuclear magnetic resonance (NMR) to be a facial bidentate complex. Cobalt(III)H2O(NH3)3 adenosine diphosphate has been resolved into lambda and delta isomers by chromatography on cycloheptaamylose. Both the lambda and delta forms are a pair of isomers that are not separated by cycloheptaamylose, reverse phase high-pressure liquid chromatography (HPLC), or cation exchange chromatography. These isomers presumably represent syn- and anti-arrangement of coordinated water and adenosine.
通过质子和³¹P核磁共振（NMR）已表明，焦磷酸钴（III）H₂O（NH₃）₃是一种面式双齿配合物。钴（III）H₂O（NH₃）₃二磷酸腺苷已通过在环糊精上的色谱法拆分为λ和δ异构体。λ和δ形式均为一对异构体，它们不能通过环糊精、反相高压液相色谱（HPLC）或阳离子交换色谱法分离。这些异构体可能代表配位水和腺苷的顺式和反式排列。
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